Silane Coupling Agents

Silane coupling agents are organosilicone compounds having two functional groups with different reactivity. One of the two functional groups reacts with organic materials and the other reacts with inorganic materials. Their general structure is as follows:

where Y denotes a functional group that links with organic materials, e.g. vinyl, epoxy, amino group and so on. X is a functional group that undergoes hydrolysis by water or moisture to form silanol. This silanol links with inorganic materials. Representative examples of X include chlorine, alkoxy, and
acetoxy group.
Silane coupling agents are effective for the improved adhesion at the interface between the organic and inorganic materials and have been frequently utilized to enhance the strength and improve the performance of glass-fiber reinforced plastics. Recently, they have been used in the manufacture of inorganic-organic hybrid materials such as the laminating board for printed circuit boards, artificial marble, plastic magnets, and silica-immobilized bioactive compounds.
In addition to the original purpose of improving the adhesiveness of an interface, different applications are being explored. Examples include synthesis of moisture crosslinkable polymers using the reactivity of hydrolytic functional group, to give antistatic and antibacterial properties from surface treatment using silane coupling agents. It is expected that silane coupling agents will be applied in many fields.

Vinyl Group

Epoxy Group

Amino Group

Others

Intermediates

Vinyl Group

A0785 A0785 A1504 A1504 D2318 D2318
D3386 D3386 T0407 T0407 V0044 V0044
V0042 V0042 V0048 V0048
A0785 Allyltriethoxysilane
A1504 Allyltrimethoxysilane
D2318 Diethoxymethylvinylsilane
D3386 Dimethoxymethylvinylsilane
T0407 Trichlorovinylsilane
V0044 Triethoxyvinylsilane
V0042 Vinyltrimethoxysilane
V0048 Vinyltris(2-methoxyethoxy)silane

Epoxy Group

D2632 D2632 G0261 G0261 G0210 G0210
D2632 Diethoxy(3-glycidyloxypropyl)methylsilane
G0261 3-Glycidyloxypropyl(dimethoxy)methylsilane
G0210 3-Glycidyloxypropyltrimethoxysilane

Amino Group

A0876 A0876 A1923 A1923 A0774 A0774
D1980 D1980 A0439 A0439 T1255 T1255
P1458 P1458 T2246 T2246 T2796 T2796
A0876 3-(2-Aminoethylamino)propyldimethoxymethylsilane
A1923 3-(2-Aminoethylamino)propyltriethoxysilane
A0774 3-(2-Aminoethylamino)propyltrimethoxysilane
D1980 3-Aminopropyldiethoxymethylsilane
A0439 3-Aminopropyltriethoxysilane
T1255 3-Aminopropyltrimethoxysilane
P1458 Trimethoxy[3-(phenylamino)propyl]silane
T2246 Trimethyl[3-(triethoxysilyl)propyl]ammonium Chloride
T2796 Trimethyl[3-(trimethoxysilyl)propyl]ammonium Chloride (ca. 50% in Methanol)

Others

C1402 C1402 C1168 C1168 C0844 C0844
T1253 T1253 E0327 E0327 M1323 M1323
M1505 M1505 M0928 M0928 T2705 T2705
T2577 T2577 I0556 I0556 T2676 T2676
T1770 T1770 A1597 A1597 C0840 C0840
M0725 M0725 T1915 T1915 T2720 T2720
U0048 U0048 V0050 V0050
C1402 (Chloromethyl)triethoxysilane
C1168 3-Chloropropyldimethoxymethylsilane
C0844 3-Chloropropyltrichlorosilane
T1253 3-Chloropropyltriethoxysilane
E0327 2-(3,4-Epoxycyclohexyl)ethyltrimethoxysilane
M1323 3-Mercaptopropyl(dimethoxy)methylsilane
M1505 (3-Mercaptopropyl)triethoxysilane
M0928 (3-Mercaptopropyl)trimethoxysilane
T2705 Trichloro(1H,1H,2H,2H-heptadecafluorodecyl)silane
T2577 Trichloro(1H,1H,2H,2H-tridecafluoro-n-octyl)silane
I0556 3-(Triethoxysilyl)propyl Isocyanate
T2676 3-(Triethoxysilyl)propyl Methacrylate
T1770 Triethoxy-1H,1H,2H,2H-tridecafluoro-n-octylsilane
A1597 3-(Trimethoxysilyl)propyl Acrylate (stabilized with BHT)
C0840 3-Trimethoxysilylpropyl Chloride
M0725 3-(Trimethoxysilyl)propyl Methacrylate (stabilized with BHT)
T1915 1-[3-(Trimethoxysilyl)propyl]urea
T2720 Trimethoxy(3,3,3-trifluoropropyl)silane
U0048 3-Ureidopropyltriethoxysilane (40-52% in Methanol)
V0050 N-[2-(N-Vinylbenzylamino)ethyl]-3-aminopropyltrimethoxysilane Hydrochloride (30-40% in Methanol)

Intermediates

B0393 B0393 C1259 C1259 C0892 C0892
D1486 D1486 D1553 D1553 D0454 D0454
D1052 D1052 D1731 D1731 D2319 D2319
D1509 D1509 D1510 D1510 E0188 E0188
H0879 H0879 O0165 O0165 O0256 O0256
O0168 O0168 O0171 O0171 P0736 P0736
P0240 P0240 T1786 T1786 T1322 T1322
H0547 H0547 M0450 M0450 O0079 O0079
P0371 P0371 T0924 T0924 E0189 E0189
M0451 M0451 M0660 M0660 P0857 P0857
T1801 T1801
B0393 Butyltrichlorosilane
C1259 2-Cyanoethyltriethoxysilane
C0892 Cyclohexyltrichlorosilane
D1486 Decyltrichlorosilane
D1553 Diacetoxydimethylsilane
D0454 Diethoxydimethylsilane
D1052 Dimethoxydimethylsilane
D1731 Dimethoxydiphenylsilane
D2319 Dimethoxymethylphenylsilane
D1509 Dodecyltrichlorosilane
D1510 Dodecyltriethoxysilane
E0188 Ethyltrichlorosilane
H0879 Hexyltrimethoxysilane
O0165 Octadecyltriethoxysilane
O0256 Octadecyltrimethoxysilane
O0168 n-Octyltrichlorosilane
O0171 n-Octyltriethoxysilane
P0736 Pentyltriethoxysilane
P0240 Phenyltrichlorosilane
T1786 Triacetoxymethylsilane
T1322 Trichloro-2-cyanoethylsilane
H0547 Trichlorohexylsilane
M0450 Trichloro(methyl)silane
O0079 Trichlorooctadecylsilane
P0371 Trichloro(propyl)silane
T0924 Trichlorotetradecylsilane
E0189 Triethoxyethylsilane
M0451 Triethoxymethylsilane
M0660 Trimethoxy(methyl)silane
P0857 Trimethoxyphenylsilane
T1801 Trimethoxy(propyl)silane


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