Copper(I) Trifluoromethanesulfonate Benzene Complex

Synonym : Copper(I) Triflate Benzene Complex

Synonym : Trifluoromethanesulfonic Acid Copper(I) Salt Benzene Complex

Structure

Copper(I) Trifluoromethanesulfonate Benzene Complex
General Information
TCI Product No. : T1442
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
1G 55.40 GBP 2 4
5G 171.50 GBP Please contact us. 3

Status at 02:00 a.m. on 10 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days
Purity / Analysis Method : >90.0%(T)
Storage : Refrigerator
M.F. / M.W. : CCuF3O3S.1/2C6H6=251.67
CAS Number : 42152-46-5
Related CAS Number :
MDL Number : MFCD00043300
Application

Photocycloaddition

Photocycloaddition
  • R. G. Salomon, J. K. Kochi, Tetrahedron Lett., 1973, 2529; R. G. Salomon, K. Folting, W. E. Streib, J. K. Kochi, J. Am. Chem. Soc., 1974, 96, 1145; R. G. Salomon, D. J. Coughlin, E. M. Easler, J. Am. Chem. Soc., 1979, 101, 3961; R. G. Salomon, S. Ghosh, Org. Synth., Coll. Vol. 7, 177; R. G. Salomon, J. K. Kochi, J. Chem. Soc., Chem. Commun., 1972, 559; idem., J. Am. Chem. Soc., 1973, 95, 3300.
References
F & F : 12, 144
EC Number : 255-686-6
Transport Information
UNNo. : 3175
Class : 4.1
PG : II
Safety
Signal Word : Warning
Pictogram : Flame Exclamation Mark
GHS H Statement : Flammable solid. Causes skin irritation. Causes serious eye irritation.
GHS P Statement : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Gently wash with plenty of soap and water. Wear protective gloves/eye protection/face protection. If skin irritation occurs: Get medical advice/attention. Wash hands thoroughly after handling. If eye irritation persists: Get medical advice/attention.
Risk Phrases
R11 : Highly flammable.
R36/37/38 : Irritating to eyes, respiratory system and skin.
Safety Phrases
S16 : Keep away from sources of ignition - No smoking.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33 : Take precautionary measures against static discharges.
S36 : Wear suitable protective clothing.
Informative Links
Related Categories :
Structure of Chemicals Classes of Metal Compounds Transition Metal Compounds Cu (Copper) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Copper
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Triflates

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