Structure
| TCI Product No. : | T1350 | ||||||||||||||||||
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| Stock Status : |
Status at 02:00 a.m. on 07 Feb 2012 * Items available from stock in Japan will be delivered in 10 business days |
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| Purity / Analysis Method : | >97.0%(T) | ||||||||||||||||||
| Storage : | Freezer | ||||||||||||||||||
| M.F. / M.W. : | C72H60P4Pd=1155.59 | ||||||||||||||||||
| CAS Number : | 14221-01-3 | ||||||||||||||||||
| Related CAS Number : | |||||||||||||||||||
| MDL Number : | MFCD00010012 | ||||||||||||||||||
Palladium-Catalyzed Three-Component Reaction for the Synthesis of Imidazolidinones Typical Procedure: Once the Schlenk tube containing K2CO3 (55 mg, 0.40 mmol) is flamed, dried, and filled with argon, Pd(PPh3)4 (12 mg, 0.010 mmol), PMB-protected 2,3-allenylamine (37 mg, 0.20 mmol), iodobenzene (58 mg, 0.28 mmol), phenyl isocyanate (36 mg, 0.30 mmol), and CH3CN (4 mL) are added sequentially. The resulting solution is heated to and stirred at 70°C. When the reaction is completed as monitored by TLC, the solvent is evaporated under reduced pressure, and the residue is purified by chromatography on silica gel (petroleum ether : ethyl acetate = 7:1) to afford the corresponding imidazolidione (72 mg, Y. 96%) as an oil. |
| Beilstein : | 16(4)954 |
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| F & F : | 12, 468 |
| EC Number : | 238-086-9 |
| S22 : | Do not breathe dust. |
| S24/25 : | Avoid contact with skin and eyes. |
| TCI Product Literature : | |
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| Related Categories : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Pd (Palladium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Palladium Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Palladium Catalyst (for Suzuki-Miyaura Cross-coupling) |