2-(Di-tert-butylphosphino)biphenyl

Synonym : (2-Biphenylyl)di-tert-butylphosphine

Synonym : JohnPhos

Structure

2-(Di-tert-butylphosphino)biphenyl
General Information
TCI Product No. : D3387
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
1G 63.75 GBP 2 >10

Status at 02:00 a.m. on 11 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days

Purity / Analysis Method : >98.0%(GC)
Storage :
M.F. / M.W. : C20H27P=298.41
CAS Number : 224311-51-7
Related CAS Number :
MDL Number : MFCD01862440
Data of Reference
mp : 87 °C
Application

Vinylation of aryl bromides

Vinylation of aryl bromides
  • S. E. Denmark, C. R. Butler, Org. Lett., 2006, 8, 63.
Safety
Signal Word : Warning
Pictogram : Exclamation Mark
GHS H Statement : Causes skin irritation. Causes serious eye irritation.
GHS P Statement : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash hands thoroughly after handling. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Risk Phrases
R36/37/38 : Irritating to eyes, respiratory system and skin.
Safety Phrases
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 : Wear suitable protective clothing.
Informative Links
TCI Product Literature :
Related Categories :
Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Phosphine Ligands (for Suzuki-Miyaura Cross-coupling)
Synthetic Organic Chemistry Phosphines
Synthetic Organic Chemistry Ligands Phosphine Ligands
Synthetic Organic Chemistry Ion-Catalyzed Oraganic Synthesis Ligands Phosphine Ligands