Dess-Martin Periodinane

Synonym : 1,1,1-Triacetoxy-1,1-dihydro-1,2-benziodoxol-3(1H)-one

Certificate of Analysis

About Lot Numbers

MSDS[PDF]

General Information

TCI Product No. :

D2045

Stock Status :

Status at 02:00 a.m. on 11 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days

Purity / Analysis Method :

>95.0%(T)

Storage :

Freezer

M.F. / M.W. :

C13H13IO8=424.14

CAS Number :

87413-09-0

Related CAS Number :

MDL Number :

MFCD00130127

Application
Dess-Martin Periodinane Reagent M. Horikawa, K. Hashimoto, H. Shirahama, Tetrahedron Lett. 1993, 34, 331. J. N. Haseltine, M. P. Cabal, N. B. Mantlo, N. Iwasawa, D. S. Yamashita, R. S. Coleman, S. J. Danishefsky, G. K. Schulte, J. Am. Chem. Soc. 1991, 113, 3850. J. P. Burkhart, N. P. Peet, P. Bey, Tetrahedron Lett. 1988, 29, 3433. D. B. Dess, J. C. Martin, J. Org. Chem. 1983, 48, 4155. R. J. Linderman, D. M. Graves, Tetrahedron Lett. 1987, 28, 4259.

References
Merck Index(14) :	2933
F & F :	17, 271

Safety
Signal Word :	Danger
Pictogram :
GHS H Statement :	May cause fire or explosion; strong oxidizer. Causes skin irritation. Causes serious eye irritation.
GHS P Statement :	IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Gently wash with plenty of soap and water. Wear protective gloves/eye protection/face protection. If skin irritation occurs: Get medical advice/attention. Wash hands thoroughly after handling. If eye irritation persists: Get medical advice/attention.

Risk Phrases
R36/37/38 :	Irritating to eyes, respiratory system and skin.
R8 :	Contact with combustible material may cause fire.

Safety Phrases
S17 :	Keep away from combustible material.
S26 :	In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 :	Wear suitable protective clothing.

Informative Links
TCI Product Literature :	Hypervalent Iodine Compounds[PDF]
Related Categories :	Synthetic Organic Chemistry Hypervalent Iodine Compounds Functional Materials Oxidation Oxidation Agents Hypervalent Iodine Compounds (Oxidation)