Dimethyl Sulfide Borane

Synonym : Borane - Dimethyl Sulfide Complex

Synonym : DMSB

Synonym : Methyl Sulfide Borane

Structure

Dimethyl Sulfide Borane
General Information
TCI Product No. : D1843
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
25ML 51.80 GBP 3 >10

Status at 02:00 a.m. on 11 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days
Purity / Analysis Method : >90.0%(T)
Storage : Refrigerator
M.F. / M.W. : C2H6S.BH3=75.96
CAS Number : 13292-87-0
Related CAS Number :
MDL Number : MFCD00013189
Data of Reference
d : 0.80
fp : 18 °C
Application

Hydroboration

Hydroboration
  • S. Saito, T. Hasegawa, M. Inaba, R. Nishida, T. Fujii, S. Nomizu, T. Moriwake, Chem. Lett., 1984, 1389; L. M. Braun, R. A. Braun, H. R. Crissman, M. Opperman, R. M. Adams, J. Org. Chem., 1971, 36, 2388; C. F. Lane, J. Org. Chem., 1974, 39, 1437; R. O. Hutchins, F. Cistone, Org. Prep. Proced. Int., 1981, 13, 225; C. F. Lane, J. Org. Chem., 1974, 39, 1437; C. F. Lane, J. J. Daniels, Org. Synth., Coll. Vol., 1988, 6, 719; H. C. Brown, J. V. N. Vara Prasad, S-H. Zee, J. Org. Chem., 1986, 51, 439.
References
Beilstein : 1(4)1277
F & F : 11, 69
RTECS# : PV5080000
EC Number : 236-313-6
Transport Information
UNNo. : 3399
Class : 4.3 / 3
PG : I
Safety
Signal Word : Danger
Pictogram : Flame Corrosion
GHS H Statement : Highly flammable liquid and vapour. In contact with water releases flammable gases which may ignite spontaneously. Causes serious eye damage.
GHS P Statement : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. In case of fire: Do not use water for extinction. Wear protective gloves/eye protection/face protection. Immediately call a POISON CENTER or doctor/physician. Store in a dry place. Store in a closed container.
Risk Phrases
R11 : Highly flammable.
R14/15 : Reacts violently with water, liberating extremely flammable gases.
R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed.
R36/37/38 : Irritating to eyes, respiratory system and skin.
Safety Phrases
S16 : Keep away from sources of ignition - No smoking.
S23 : Do not breathe gas/fumes/vapour/spray (appropriate wording to be specified by the manufacturer).
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S33 : Take precautionary measures against static discharges.
S36/37/39 : Wear suitable protective clothing, gloves and eye/face protection.
S43 : In case of fire, use ... (indicate in the space the precise type of fire-fighting equipment. If water increases risk, add 'Never use water').
Informative Links
Related Categories :
Structure of Chemicals B (Classes of Boron Compounds) Boranes
Synthetic Organic Chemistry Reducing Agents Boranes Borane Complex

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