Structure
| TCI Product No. : | C2346 | ||||||||||||||
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| Stock Status : |
Status at 02:00 a.m. on 11 Feb 2012 * Items available from stock in Japan will be delivered in 10 business days |
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| Purity / Analysis Method : | >95.0%(T) | ||||||||||||||
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| M.F. / M.W. : | C4H6CuO4.H2O=181.63 (as Anhydrous) | ||||||||||||||
| CAS Number : | 6046-93-1 | ||||||||||||||
| Related CAS Number : | 142-71-2 | ||||||||||||||
| MDL Number : | MFCD00149570 | ||||||||||||||
Synthesis of Carbinols Typical procedure: Under an air atmosphere, a Schlenk tube is charged with Cu(OAc)2•H2O (4.0 mg, 0.02 mmol), dppf (16.6 mg, 0.03 mmol), arylboronic acid (0.4 mmol), aldehyde (0.2 mmol), NaOAc (49.2 mg, 0.6 mmol), and toluene (3 mL) under ice-salt (-20 ºC). The mixture is stirred for 0.5 h at room temperature, refluxed for 24 h, and then cooled in a Schlenk tube to room temperature. The mixture is extracted with ethyl acetate (4×5 mL), and the organic layers are washed with water. The organic layers are dried over MgSO4, concentrated, and purified by flash column chromatography on silica gel to give the desired product. |
| Beilstein : | 2(4)94 |
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| RTECS# : | AG3500000 |
| UNNo. : | 3077 |
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| Class : | 9 |
| PG : | III |
| Signal Word : | Warning |
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| Pictogram : |
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| GHS H Statement : | Harmful if swallowed. Toxic to aquatic life. Toxic to aquatic life with long lasting effects. |
| GHS P Statement : | Avoid release to the environment. Wash hands thoroughly after handling. IF SWALLOWED: Call a POISON CENTER or doctor/physician if you feel unwell. Rinse mouth. Collect spillage. Dispose of contents/container through a waste management company authorized by the local government Do not eat, drink or smoke when using this product. |
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