(Chloromethyl)isopropoxydimethylsilane

Synonym : (Chloromethyl)dimethylisopropoxysilane

Structure

(Chloromethyl)isopropoxydimethylsilane
General Information
TCI Product No. : C1370
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
5ML 25.65 GBP 1 >10
25ML 80.40 GBP Please contact us. >10

Status at 02:00 a.m. on 11 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days
Purity / Analysis Method : >96.0%(GC)
Storage :
M.F. / M.W. : C6H15ClOSi=166.72
CAS Number : 18171-11-4
Related CAS Number :
MDL Number : MFCD00010605
Data of Reference
bp : 145 °C
d : 0.93
fp : 28 °C
Application

Nucleophilic Hydroxymethylation

Nucleophilic Hydroxymethylation
  • K. Tamao, N. Ishida, Tetrahedron Lett., 1984, 25, 4245; K. Tamao, N. Ishida, Y. Ito, M. Kumada, Org. Synth., 1990, 69, 96; T. Konosu, T. Miyaoka, Y. Tajima, S. Oida, Chem. Pharm. Bull., 1991, 39, 2241; G. J. P. H. Boons, P. A. M. van der Klein, G. A. van der Marel, J. H. van Boom, Recl. Trav. Chim. Pays-Bas, 1988, 107, 507; G. J. P. H. Boons, G. A. van der Marel, J. T. Poolman, J. H. van Boom, ibid., 1989, 108, 339.
References
F & F : 14, 186
Transport Information
UNNo. : 1993
Class : 3
PG : III
Safety
Signal Word : Warning
Pictogram : Flame Exclamation Mark
GHS H Statement : Flammable liquid and vapour. Causes skin irritation. Causes serious eye irritation.
GHS P Statement : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN (or hair): Remove/Take off immediately all contaminated clothing. Rinse skin with water/shower. Wear protective gloves/eye protection/face protection. If skin irritation occurs: Get medical advice/attention. Wash hands thoroughly after handling. If eye irritation persists: Get medical advice/attention.
Risk Phrases
R10 : Flammable.
R36/37/38 : Irritating to eyes, respiratory system and skin.
Safety Phrases
S16 : Keep away from sources of ignition - No smoking.
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 : Wear suitable protective clothing.
Informative Links
Related Categories :
Structure of Chemicals Si (Classes of Silicon Compounds) Si-O Compounds Monoalkoxysilanes
Synthetic Organic Chemistry Silicon Compounds (for Synthesis)

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