Bis(tri-tert-butylphosphine)palladium(0)

Structure

Bis(tri-tert-butylphosphine)palladium(0)
General Information
TCI Product No. : B3161
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
250MG 136.95 GBP 2 >10
1G 342.30 GBP Please contact us. >10

Status at 02:00 a.m. on 10 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days
Purity / Analysis Method : >98.0%(T)
Storage : Freezer
M.F. / M.W. : C24H54P2Pd=511.06
CAS Number : 53199-31-8
Related CAS Number :
MDL Number : MFCD03094580
Application

Newman-Kwart Rearrangement of Thiocarbamates

Newman-Kwart Rearrangement of Thiocarbamates

Typical Procedure: An ampoule is charged with the thiocarbamate (0.442 mmol) and anhydrous degassed toluene (4 mL) is added via gastight syringe under nitrogen with stirring. A J. Youngs valve is fitted and the ampoule is placed into an oil bath pre-equilibrated at 100℃. After ca. 5 minutes the valve is removed and Pd(t-Bu3P)2 (2 mol%, 0.00884 mmol) is added as a solid, the valve is then replaced and the reaction mixture heated for 2.5 hours. A sample of the reaction mixture is removed via gastight syringe and found to contain the desired product (＞99%).
Informative Links
TCI MAIL :
TCI Product Literature :
Related Categories :
Structure of Chemicals Classes of Metal Compounds Transition Metal Compounds Pd (Palladium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Palladium
Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Palladium Catalyst (for Suzuki-Miyaura Cross-coupling)

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