(R,R)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane

Synonym : (R,R)-DIPAMP

Synonym : (R,R)-Ethylenebis[(2-methoxyphenyl)phenylphosphine]

Structure

(R,R)-1,2-Bis[(2-methoxyphenyl)phenylphosphino]ethane
General Information
TCI Product No. : B3035
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
100MG 56.60 GBP 2 2
1G 339.30 GBP 1 6

Status at 02:00 a.m. on 11 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days

Purity / Analysis Method : >97.0%(GC)(T)
Storage :
M.F. / M.W. : C28H28O2P2=458.48
CAS Number : 55739-58-7
Related CAS Number :
MDL Number : MFCD05863546
Data of Reference
mp : 104 °C
[α]20D : -85 ° (C=1, CHCl3)
Application

P Chiral Ligand

P Chiral Ligand
  • W. S. Knowles, M. J. Sabacky, B. D. Vineyard, D. J. Weinkauff, J. Am. Chem. Soc. 1975, 97, 2567; B. D. Vineyard, W. S. Knowles, M. J. Sabacky, G. L. Bachman, D. J. Weinkauff, J. Am. Chem. Soc. 1977, 99, 5946.
Safety
Signal Word : Warning
Pictogram : Exclamation Mark
GHS H Statement : Causes skin irritation. Causes serious eye irritation.
GHS P Statement : IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. IF ON SKIN: Gently wash with plenty of soap and water. If skin irritation occurs: Get medical advice/attention. Wash hands thoroughly after handling. If eye irritation persists: Get medical advice/attention. Take off contaminated clothing and wash before reuse.
Risk Phrases
R36/37/38 : Irritating to eyes, respiratory system and skin.
Safety Phrases
S26 : In case of contact with eyes, rinse immediately with plenty of water and seek medical advice.
S36 : Wear suitable protective clothing.
Informative Links
TCI MAIL :
Related Categories :
Synthetic Organic Chemistry Asymmetric Synthesis
Synthetic Organic Chemistry Phosphines
Synthetic Organic Chemistry Ligands Phosphine Ligands