Bis(acetonitrile)palladium(II) Dichloride

Synonym : Dichlorobis(acetonitrile)palladium(II)

General Information
TCI Product No. : B1676
Stock Status :
Unit Sizes Price Available stock
Belgium Tokyo *
1G 62.50 GBP 4 >10
5G 219.10 GBP 1 >10

Status at 02:00 a.m. on 10 Feb 2012

* Items available from stock in Japan will be delivered in 10 business days
Purity / Analysis Method : >98.0%(T)
Storage :
M.F. / M.W. : C4H6Cl2N2Pd=259.43
CAS Number : 14592-56-4
Related CAS Number :
MDL Number : MFCD00013122
Application

Synthesis of Oxindoles

Synthesis of Oxindoles

Typical Procedure: To a dried screw-cap vial is added anilide (0.3 mmol), AgOCOCF3 (132.5 mg, 0.6 mmol), (CH3CN)2PdCl2 (3.5 mg, 0.015 mmol) and chlorobenzene. The reaction mixture is stirred at 100-120 °C for 3-12 h in a pre-heated oil bath. After cooling to room temperature, the reaction is diluted with EtOAc and filtered with a glass filter. The filtrate is washed with 5% aqueous NaHCO3 and brine. The extract is dried over MgSO4 and concentrated in vacuo. The crude is purified by preparative TLC.

References
F & F : 14, 35
EC Number : 238-637-3
Transport Information
UNNo. : 3439
Class : 6.1
PG : III
Safety
Signal Word : Danger
Pictogram : Skull and Crossbones
GHS H Statement : Toxic by inhalation, in contact with skin and if swallowed.
GHS P Statement : IF SWALLOWED: Immediately call a POISON CENTER or doctor/physician. Rinse mouth. IF ON SKIN: Gently wash with plenty of soap and water. Avoid breathing. Wear protective gloves/protective clothing/eye protection/face protection. IF INHALED: Remove victim to fresh air and keep at rest in a position comfortable for breathing. Call a POISON CENTER or doctor/physician. Wash hands thoroughly after handling.
Risk Phrases
R20/21/22 : Harmful by inhalation, in contact with skin and if swallowed.
Safety Phrases
S22 : Do not breathe dust.
S36/37 : Wear suitable protective clothing and gloves.
Informative Links
TCI Product Literature :
Related Categories :
Structure of Chemicals Classes of Metal Compounds Transition Metal Compounds Pd (Palladium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Palladium
Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Palladium Catalyst (for Suzuki-Miyaura Cross-coupling)

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