Structure
| TCI Product No. : | A1424 | ||||||||||||||
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| Stock Status : |
Status at 02:00 a.m. on 07 Feb 2012 * Items available from stock in Japan will be delivered in 10 business days |
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| Purity / Analysis Method : | >98.0%(T) | ||||||||||||||
| Storage : | |||||||||||||||
| M.F. / M.W. : | C4H6O4Pd=224.51 | ||||||||||||||
| CAS Number : | 3375-31-3 | ||||||||||||||
| Related CAS Number : | |||||||||||||||
| MDL Number : | MFCD00012453 | ||||||||||||||
Arylations of Indoles Palladium-Catalyzed One-Pot Synthesis of Indoles from 2-Iodobenzoic Acid Synthesis of aromatic esters via Pd-catalyzed decarboxylative coupling with bidentate phosphine ligands Typical procedure: A 10 mL oven-dried Schlenk tube is charged with Pd(OAc)2 (0.005 mmol), 1,3-bis(diphenylphosphino)propane (0.0075 mmol), and potassium ethyl oxalate (0.75 mmol). The tube is evacuated and backfilled with argon. Bromobenzene (0.5 mmol) and 1-methyl-2-pyrrolidone (1.0 mL), are added by syringe at room temperature. The tube is then sealed and the mixture is allowed to stir under 1 atm of argon at 150ºC for 24 h (the tube is connected to the Schlenk line which is filled with argon so that CO2 can be released to air). |
| Merck Index(14) : | 6991 |
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| RTECS# : | AJ1900000 |
| EC Number : | 222-164-4 |
| Signal Word : | Warning |
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| Pictogram : |
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| GHS H Statement : | May be harmful if swallowed. Causes serious eye irritation. |
| GHS P Statement : | IF IN EYES: Rinse cautiously with water for several minutes. Remove contact lenses, if present and easy to do. Continue rinsing. Wash hands thoroughly after handling. If eye irritation persists: Get medical advice/attention. Call a POISON CENTER or doctor/physician if you feel unwell. Wear protective gloves/eye protection/face protection. |
| R38 : | Irritating to skin. |
| R41 : | Risk of serious damage to eyes. |
| S26 : | In case of contact with eyes, rinse immediately with plenty of water and seek medical advice. |
| S36/37/39 : | Wear suitable protective clothing, gloves and eye/face protection. |
| TCI Product Literature : | |
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| Related Categories : |
Structure of Chemicals
Classes of Metal Compounds
Transition Metal Compounds
Pd (Palladium) Compounds
Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Metal Complexes Synthetic Organic Chemistry Catalysts for Organic Synthesis Homogeneous Catalysts Palladium Synthetic Organic Chemistry Suzuki-Miyaura Cross-coupling Palladium Catalyst (for Suzuki-Miyaura Cross-coupling) Functional Materials Oxidation Environmentally-friendly Oxidation Transition Metal Complexes (Environmentally-friendly Oxidation) |